Search results for "Vibrational excitations"

On the study of the vibrational energy levels of Arsine molecule

2008

Abstract We compare two formalisms applied to the vibrational modes of the molecule of AsH 3 of C 3 v molecular symmetry group. Indeed, the close stretching modes of this molecule may be considered as those of a three-dimensional oscillator whereas the bending modes may be considered either as a one-dimensional oscillator of symmetry A 1 and a two-dimensional oscillator of symmetry E or as an approximate three-dimensional oscillator. So, we have applied the U ( p  + 1) formalism to the both stretching and bending modes and introduced coupling terms acting on an appropriate coupled vibrational basis through a local mode formalism. We have then compared the result of our fitting with those ob…